Keep container tightly closed. Manufacturers and importers of formaldehyde/formalin need to ensure that hazardous chemicals are labelled and that safety data sheets are prepared and provided. endobj Emergency and supportive measures: 1. Vapors may form explosive mixtures with air. Refer immediately for medical attention. One of the most common uses of formaldehyde in the U.S is manufacturing urea-formaldehyde resins, used in particleboard products. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Commercial formaldehyde-alcohol solutions are stable. SARA: Section 355 (extremely hazardous substances): 50-00-0 formaldehyde. Using OECD Guide-line 301D (Ready Biodegradability: Closed Bottle Test), formaldehyde achieved 90% in 28 days using non-acclimated inoculum which classified the compound as readily biodegradable(2). Odour Threshold: 0,05 – 0,125 ppm (Formaldehyde) pH: 2,8 – 4,0 at 20°C Melting point: < -15°C Boiling point/boiling range: 93-96°C at 1.013 hPa Flash point: 62°C Method: c.c Evaporation rate: No information available Flammability (solid, gas): No information available LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 info@labchem.com - … Reacts with nitrogen oxides at about 180; the reaction becomes explosive. It is used as a denaturant in formaldehyde-agarose gel electrophoresis of RNA. Formaldehyde (Formalin) 50-00-0 200-001-8 5.00 % v/v T - Toxic. Formaldehyde Solution Flinn Scientific, Inc. P.O. The Working Group was not in full agreement on the evaluation of formaldehyde causing leukaemias in humans, with a small majority viewing the evidence as sufficient of carcinogenicity and the minority viewing the evidence as limited. Wash and dry hands. Hazard class: Flammable liquids (Category 3). C - Corrosive. (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: Flammable/combustible material. Metals such as platinium, copper, chromia, and alumina also catalyze the formation of methanol, methylformate, formic acid, carbon dioxide, and methane. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. Formaldehyde gas adsorbs on clay minerals to a degree at high gas concentrations which is an important quality in its use as a soil fumigant(4). Flammable solid. Can react with hydrogen chloride or other inorganic chlorides to form bis-chloromethylether (BCME), a known carcinogen. DOWNLOAD MSDS (PDF) | Search MSDS currently available for download bioWORLD offers Formaldehyde (4%) in PBS for your research at low price. May react with hydrochloric acid to form highly toxic bis(chloromethyl) ether. Do NOT induce vomiting. The PCBU must also obtain a copy of the safety data sheet and make it readil… Formaldehyde, 37% w/w Safety Data Sheet according to Federal Register / Vol. Vapour is heavier than air and is an explosion hazard. Safety glasses with side-shields conforming to EN166. Handle in accordance with good industrial hygiene and safety practice. 3 (H301 + H311 + H331), Skin Corr. P280 Wear protective gloves/protective clothing/eye protection/face protection. 1B (H350) Concentration: < 5% Component: Methanol CAS No: 67-56-1 EC No: 200-659-6 Index No: 603-001 -00-x Registration No: 01-2119433307 -44-xxxx Classification: Flam. FORMALDEHYDE 37-40% W/V LRG Protective actions during firefighting Avoid breathing fire gases or vapours. 1B (H314), Skin Sens. Vapor explosion hazard indoors, outdoors or in sewers. There is sufficient evidence in humans for the carcinogenicity of formaldehyde. : 605-001-00-5 REACH No. Polymerization reaction with phenol may develop sudden destructive pressure [Bretherick, 5th ed., 1995, p.168]. 3. Half-upright position. Component: Formaldehyde CAS No: 50-00-0 EC No: 200-001-8 Index No: 605-001 -00-5 Classification: Acute Tox. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Formaldehyde, Lab Grade Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com SECTION 1: Identification of the substance/mixture and of the supplier Product name: Formaldehyde, Lab Grade Manufacturer/Supplier Trade name: Manufacturer/Supplier Article number: S25329 Recommended uses of the product and restrictions on use: Manufacturer Details: … P363 Wash contaminated clothing before reuse. Separated from incompatible materials. It also has minor uses in agriculture, as an analytical reagent, in concrete and plaster additives, cosmetics, disinfectants, fumigants, photography, and wood preservation. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, H314 Causes severe skin burns and eye damage, H341 Suspected of causing genetic defects. SDS # :012612 Airgas USA, LLC … General description Formaldehyde (formalin) is produced by oxidation of methanol. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Use water to keep fire exposed containers cool. High formaldehyde concentration or methanol content lowers flash point. Formaldehyde –urea resin is used as an insulating material in building construction. Particularly relevant to the discussions regarding sufficient evidence was a recent study accepted for publication which, for the first time, reported aneuploidy in blood of exposed workers characteristic of myeloid leukaemia and myelodysplastic syndromes, with supporting information suggesting a decrease in the major circulating blood-cell types and in circulating haematological precursor cells. P301+P330+P331 IF SWALLOWED: Rinse mouth. Will polymerize violently in the presence of caustics and nitrides; (amines) exothermic reaction, (Azo compound) exothermic reaction giving off nitrogen gas, (caustics) heat generation and violent polymerization, (dithiocarbamates) formation of flammable gases and toxic fumes, formation of carbon disulfide may result, (alkali and alkaline earth metals) heat generation and formation of a flammable hydrogen gas. It is made of 37% formaldehyde and impurities such as methanol, small amounts of formic acid, aldehydes and ketones. Ingestion. P308+P313 IF exposed or concerned: Get medical advice/ attention. Ensure adequate ventilation. 2-3 ppm, mild tingling of eyes. Recommended Exposure Limit: 10 Hour Time-Weighted Average: 0.016 ppm. CERCLA: Formaldehyde 50-00-0: RQ = 100 lbs (45.4 Kg). Higher concentrations or splashes may cause irreversible eye damage. xœÍ[ÝsÓH§Šÿaí=2Ö|¨­­3¶ÙMH66µÅÁ>øŒ ¾Kbλpýu÷H¶dideñőåžéÏéùuÏ0n²ÕÇù"c?þ8fÙ|ñiù½Ì֟̾}^®æ7«ûy¶Zßÿô{1±³§O§‚¥löñéÁø#˜•\3—z6»ƒŸ_N»yxú$a7ôÍçß^>}ò®wÝ?Q½eßôþX=ômoÕW½uÿÄôîáϳ%¼|ÞÿÍ~~úd̐aÁFÍ­Ü2z×cQBË­-^Ì7Àh¼? Use water spray, dry chemical, alcohol foam, or carbon dioxide. Safety Data Sheet Sodium Formaldehyde Bisulphite Solution SDS 26/7 Page n. 3 of 8 None in particular. Cat. Fireproof. 77, No. P201 Obtain special instructions before use. Flammable liquid when exposed to heat or flame; can react vigorously with oxidizers. Formaldehyde resins are used as adhesives and binders in many different industries that produce wood products, pulp and paper, synthetic fibres, plastics and coating and textiles. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Use of the substance/mixture : For laboratory and manufacturing us e only. P202 Do not handle until all safety precautions have been read and understood. R43- May cause sensitization by skin contact. Contact with substance may cause severe burns to skin and eyes. Remove contaminated clothes. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). P270 Do not eat, drink or smoke when using this product. Formaldehyde exposure can also happen in offices and newly constructed homes via off-gas from wood products, paints and finishes, and cigarette smoke. California … However, possible confounding factors were not evaluated in this study. SDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200. Use personal protective equipment. Continue rinsing. Carc. Remove contact lenses, if present and easy to do. Inhalation. <> 2. A person conducting a business or undertaking (PCBU) must correctly labelhazardous chemicals used, handled or stored at the workplace, including containers and pipework. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. Materials containing formaldehyde can release it as a gas or vapor into the air. 5.2. Aqueous solutions are unstable. P302+P352 IF ON SKIN: Wash with plenty of water/... P312 Call a POISON CENTER/doctor/\u2026if you feel unwell. c. Treat metabolic acidosis with sodium bicarbonate. Evacuate personnel to safe areas. /From table/. Formaldehyde is produced in large quantities industrially. Runoff to sewer may create fire or explosion hazard. Advice for firefighters Use suitable breathing apparatus. Identification::: Supplier's details : Nonflammable Gas Mixture: Formaldehyde 1ppb-999ppm / Nitrogen 99.9001-99. Compound will polymerize with active organic materials such as phenol. Product Name : FORMALDEHYDE SOLUTION 37 w/w, stablized with 10-12% methanol Classified as hazardous 1. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Vapors may cause dizziness or suffocation. Artificial respiration may be needed. Formalin solutions typically use up to 15% methanol as a stabilizer. 1 (H317), Muta. 1.3. Wear impervious clothing. May cause allergic respiratory and skin reaction. (ERG, 2016), Vapor or dust irritates eyes, mucous membranes, and skin; may cause dermatitis. Maintain open airway and assist ventilation if necessary. Formaldehyde: off-gas : 200-001-8: Section 3 - Hazards Identification EMERGENCY OVERVIEW. In laboratories, the gas is more commonly dissolved in water and used as an aqueous solution called formalin. Avoid oxidizing and alkaline materials. Acute exposure to formaldehyde can have a corrosive effect on the respiratory tract, gastrointestinal system, and skin. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name Formaldehyde solution, 36.5: -38% Product Number : F8775 Brand : Sigma Index-No. Administer supplemental oxygen, and observe for at least 4 to 6 hours. Evacuate danger area! Adverse reproductive effects of Formaldehyde as well as Methanol are primarily based on animal studies. It has virtually no activity for ethanol oxidation, but exhibits high activity for oxidation of long-chain primary alcohols and for oxidation of S-hydroxymethyl-glutathione, a spontaneous adduct between formaldehyde and glutathione. Methanol 67-56-1 200-659-6 1.00 % v/v F - Highly flammable. Explosion hazard: when aqueous formaldehyde solutions are heated above their flash points, a potential for explosion hazard exists. <> There is sufficient evidence in experimental animals for the carcinogenicity of formaldehyde. 5.3. Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 5.2 SDS Revision Date: 7/20/2018 5. Formaldehyde is carcinogenic to humans (Group 1). Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus. Containers may explode when heated. These reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). formaldehyde and carbon oxides). Contact causes white discoloration, smarting, cra cking and scaling. <>>> /Formaldehyde/ /Formalin (as formaldehyde)/. Formaldehyde in aqueous effluent was degraded by activated sludge and sewage in 48-72 hr(3-6). E-mail (competent person) SDS@vwr.com 1.4 Emergency phone number Telephone +44 (0) 1270 502894 (CareChem24) 2 / 14 SECTION 2: Hazard identification 2.1 Classification of the substance or mixture 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP] Hazard classes and hazard categories Hazard statements Acute toxicity, category 3, oral, dermal and inhalation … Vapors may travel to source of ignition and flash back. R11- Highly flammable. For precautions see section 2.2. Avoid breathing dust. Appearance: white powder. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. Turn off gas at source if possible. Rinse mouth. (ERG, 2016), Toxic vapors such as carbon dioxide and carbon monoxide are generated during combustion. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. P271 Use only outdoors or in a well-ventilated area. Prevent firefighting water entering watercourses or ground-water. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. An estimated BCF of 3 was calculated for formaldehyde(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). An increased incidence of menstrual disorders were observed in female workers using urea-formaldehyde resins. Wear dust mask when handling large quantities. 2 0 obj Formaldehyde (as urea formaldehyde foam) was extensively used as an insulating material until 1982 when it was banned by the U.S. Consumer Product Safety Commission. Gas. (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: May cause toxic effects if inhaled or ingested/swallowed. 2 (H341), Carc. The gas is a more dangerous fire hazard than the vapor.The gas mixes well with air, explosive mixtures are easily formed.Dust explosion possible if in powder or granular form, mixed with air. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Formaldehyde: health effects, incident management and toxicology Information on formaldehyde (also known as methanal and methylene glycol) for use in responding to chemical incidents. Studies produced a weak association (limited evidence) between adverse human female reproductive effects and occupational exposure. Synonym :Monoxide; Flue gas; Carbon oxide; carbonic oxide; Monoxide of carbon; Carbon monooxide SDS # :001014 Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone :1-866-734-3438 Section 2. Many liquids are lighter than water. Water spray may be used to flush spills away from exposures and to dilute spills to nonflammable mixtures. Do not discharge to sewer systems. Gloves must be inspected prior to use. 4-5 ppm, increased discomfort, mild lacrimation. P321 Specific treatment (see ... on this label). FIREFIGHTING MEASURES 5.1 Fire & Explosion Hazards: Will not burn, but high heat, may release formaldehyde gas which will increase the health hazards. Formaldehyde is a severe skin irritant and sensitizer. Very reactive, combines readily with many substances, 40% solution is powerful reducing agent. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. 9999% Product use :Synthetic/Analytical chemistry. MAJOR HEALTH HAZARDS:potentially fatal if inhaled, harmful on contact with the skin or swallowed, respiratory tract burns, skin burns, eye burns, allergic reactions, cancer hazard (in humans) Recommended use and restrictions on use . Reacts with peroxide, nitrogen oxide, and performic acid causing explosions. SECTION 2 — HAZARDS IDENTIFICATION. Product may generate formaldehyde which can … Avoid fluid overload in patients with inhalation exposure because of the risk of pulmonary edema. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Reacts with nitrogen oxides at about 180; the reaction becomes explosive. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. The Koc of formaldehyde is estimated as 8(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). For personal protection see section 8. Service Tel: +86-571-87759741, Marketing Tel: +86-571-89739798 skype, Copyright©2010-2021 Guidechem 浙B2-20090288-37, Recommended use of the chemical and restrictions on use, Classification of the substance or mixture, GHS label elements, including precautionary statements, Other hazards which do not result in classification, Description of necessary first-aid measures, Most important symptoms/effects, acute and delayed, Indication of immediate medical attention and special treatment needed, if necessary, Specific hazards arising from the chemical, Special protective actions for fire-fighters, Personal precautions, protective equipment and emergency procedures, Methods and materials for containment and cleaning up, Conditions for safe storage, including any incompatibilities, Individual protection measures, such as personal protective equipment (PPE), Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code, Safety, health and environmental regulations specific for the product in question, 3-Methoxy-4-(1-pyrrolidinyl)benzenediazonium trichlorozincate, polymer with formaldehyde, formaldehyde,(4-hydroxyphenyl)arsonic acid, Melamine, formaldehyde, toluenesulfonamide polymer, butylated, Benzoic acid, 2-hydroxy-, polymer with 4-(1,1-dimethylethyl)phenol and formaldehyde, sodium salt, formaldehyde; 2-methyloxirane; 4-nonylphenol; oxirane, 2,2'-Methylenebis(5,5-dimethylcyclohexane-1,3-dione), Methanethioic acid, S-1H-benzimidazol-2-yl ester (9CI), High quality Formaldehyde Cas 50-00-0 with favorable price, High Quality Formaldehyde chinese supplier, Best price Formaldehyde/Formalin/CAS:50-00-0. 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